Preparation of a Cobalt Complex Coordinated by Molecular Nitrogen and Triphenylphosphine
نویسندگان
چکیده
منابع مشابه
Preparation of a dihydrogen complex of cobalt.
Ammonia borane (AB) is an attractive candidate for the chemical storage of hydrogen. Recently, our research group reported that the complex [(pocop)IrH2] (pocop= k -C6H31,3-[OP(tBu)2]2) has facilitated the rapid release of H2 from AB under mild conditions. While this result is promising, iridium is too expensive for widespread application. Our efforts to extend the catalytic chemistry of [(poco...
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Recently, homogeneous cobalt systems were reported to catalyze the reductive silylation of dinitrogen. In this study the investigations on the silylation of dinitrogen catalyzed by CoH(PPh3)3N2 are presented. We show that in the presence of the title compound, the reaction of N2 with trimethylsilylchloride and sodium yields, on average, 6.7 equivalents of tris(trimethylsilyl)amine per Co atom i...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1967
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.40.700